None of the Athletes and the members of National Olympic Committee attended for the 2006 Lusophony Games.
| Event | Name | ||||
| 100 metres - M | Reginaldo Micha Ndong | ||||
| 1500 metres - M | Adalberto Ndong | ||||
| 1500 metres - F | Eufracia Enguru | ||||
| 5000 metres - F | Mariana Oyana | ||||
| Name | Team | ||||
| GK | Achille Pensy | ||||
| FW | Alfonso Mitogo | ||||
| Antonio Ngua Mba | Renacimiento FC | ||||
| MF | Camilo Nvo | Rayo Lasser | |||
| Diosdado Nguema | |||||
| MF | El Hadji Ibrahim Touré | Renacimiento FC | |||
| Emeterio Ekuaga | |||||
| DF | Fernando Obama | ||||
| DF | Javier Mum | Renacimiento FC | |||
| FW | Juan Simeón Esono | Sony Elá Nguema | |||
| MF | Justo Nguema | Renacimiento FC | |||
| FW | Landry Mpondo | Akonangui FC | |||
| Mahama Ichaibon | |||||
| Paul Tetty | |||||
| Ruslan Ondo | Renacimiento FC | ||||
| Santiago Maxo | |||||
| Silvano Mesian | |||||
| Valentín Asumu | |||||
| GK | Yuasa Ndong | ||||
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